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Chemistry Chapter 7 : Topic 4
Free Element Oxidation
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In a chemical reaction study, it is observed that elements such as sodium metal, chlorine gas, and oxygen gas exist independently without combining with other elements. What is the correct statement regarding their oxidation number in this state?
Reasoning: The oxidation number of any element in its free (uncombined) state is always zero, regardless of whether it is monoatomic, diatomic, or polyatomic.
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Which of the following correctly represents the oxidation number of oxygen in O₂ gas under standard conditions?
Reasoning: In elemental form (O₂), oxygen is uncombined; therefore, its oxidation number is zero.
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A student states that chlorine in Cl₂ has an oxidation number of -1 because chlorine is highly electronegative. What is the correct explanation?
Reasoning: In elemental form (Cl₂), chlorine atoms are identical and uncombined, so oxidation number is zero.
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Which of the following always has oxidation number equal to zero?
Reasoning: Elemental iron in solid state is a free element; thus oxidation number is zero.
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In which of the following species is the oxidation number of sulfur zero?
Reasoning: S₈ is elemental sulfur (free state), so oxidation number of sulfur is zero.
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Which statement best explains why noble gases have oxidation number zero in their natural form?
Reasoning: Noble gases exist as single atoms in free state, so oxidation number is zero.
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What is the oxidation number of phosphorus in white phosphorus (P₄)?
Reasoning: P₄ is elemental phosphorus; therefore, oxidation number is zero.
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A chemist analyzes graphite and diamond. What is the oxidation number of carbon in both forms?
Reasoning: Both graphite and diamond are elemental carbon forms; hence oxidation number is zero.
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Why is the oxidation number of hydrogen in H₂ gas equal to zero?
Reasoning: In H₂, hydrogen exists in free elemental form, so oxidation number is zero.
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Which of the following contains an element with oxidation number zero?
Reasoning: O₃ (ozone) is elemental oxygen; oxidation number of oxygen is zero.
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In which case is the oxidation number of an element NOT zero?
Reasoning: Na⁺ is an ion in a compound, not in free state; hence oxidation number is + 1, not zero.
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A student claims that oxidation number depends on number of atoms in the molecule. Which example disproves this?
Reasoning: Both O₂ and O₃ are elemental oxygen forms and have oxidation number zero regardless of structure.
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Which condition correctly defines “free state” of an element?
Reasoning: Free state means element is not chemically combined with other elements.
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What is the oxidation number of chlorine in elemental chlorine gas used in laboratories?
Reasoning: Cl₂ is elemental chlorine; oxidation number is zero.
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Which statement is TRUE regarding oxidation number in free elements?
Reasoning: Any element in free state always has oxidation number zero.
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Why do metals like sodium (Na) have oxidation number zero in solid form?
Reasoning: Solid sodium metal is in elemental form, so oxidation number is zero.
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Which of the following pairs both have oxidation number zero in their elemental state?
Reasoning: O₂ and Fe(s) are both elements in free state.
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A student mistakenly assigns oxidation number - 2 to oxygen in O₂. What is the correct correction?
Reasoning: In elemental form (O₂), oxidation number is zero, not – 2.
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Which of the following is NOT an example of element in free state?
Reasoning: NaCl is a compound, not elemental form.
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The oxidation number of all atoms in elemental hydrogen (H₂), oxygen (O₂), and nitrogen (N₂) is:
Reasoning: All are elemental diatomic molecules; oxidation number is zero.
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Which concept best explains why oxidation number is zero in free elements?
Reasoning: Free elements are neutral and uncombined, so oxidation number is zero.
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A chemist observes an element in nature in its pure form. What can be concluded about its oxidation number?
Reasoning: Any pure elemental form has oxidation number zero.
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