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Chemistry Chapter 9 : Topic 3
Dynamic Chemical Equilibrium
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In a chemical system, when reactants are converted into products, and at the same time products are also converting back into reactants under the same conditions, the system is said to involve a reversible reaction. If such a system is placed in a sealed container and allowed to proceed, it may eventually reach a state where no further net change is observed. Which statement correctly describes the condition at this stage?
Reasoning: At equilibrium, both forward and backward reactions continue but at equal rates, so no net change is observed.
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A student observes a reversible reaction taking place in a closed flask. After some time, the concentration of reactants and products appears constant, but molecular activity continues at the microscopic level. Which term best describes this state?
Reasoning: In dynamic equilibrium, reactions continue in both directions at equal rates, so concentrations remain constant.
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A reversible reaction is carried out in an open beaker, and gases are allowed to escape into the atmosphere. The system fails to reach equilibrium. What is the most appropriate reason?
Reasoning: A closed system is necessary for equilibrium because no reactants or products should escape or enter.
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At equilibrium in a reversible reaction, which of the following is always TRUE?
Reasoning: At equilibrium, the defining condition is equal rates of forward and reverse reactions.
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A teacher explains that even at equilibrium, molecules of reactants and products are continuously interchanging. This implies that equilibrium is:
Reasoning: Equilibrium is dynamic because reactions continue in both directions at equal rates.
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In a sealed container, nitrogen and hydrogen gases react to form ammonia. After some time, no visible change is observed in composition, although reaction continues at molecular level. What can be concluded?
Reasoning: Constant composition with ongoing reactions indicates equilibrium.
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Which statement best distinguishes equilibrium from completion of a reaction?
Reasoning: Equilibrium involves reversible reactions in both directions simultaneously.
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A student incorrectly states that at equilibrium, the amount of reactants and products must be equal. Which correction is most accurate?
Reasoning: Equilibrium depends on equal rates, not equal concentrations.
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Which condition is essential for establishing chemical equilibrium?
Reasoning: A closed system ensures no loss or gain of reactants / products.
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During equilibrium in a reversible reaction, which of the following is observed at the macroscopic level?
Reasoning: Macroscopic properties remain constant at equilibrium.
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Which statement best explains why equilibrium is called “dynamic”?
Reasoning: Both forward and reverse reactions occur continuously at equal rates.
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If a reversible reaction reaches equilibrium in a closed system, what happens to the rate of forward reaction compared to the backward reaction?
Reasoning: At equilibrium, both reaction rates are equal.
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A reaction mixture is allowed to reach equilibrium. A catalyst is then added. What is the effect on equilibrium?
Reasoning: A catalyst speeds up both directions equally and does not change equilibrium position.
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Which of the following best describes a closed system in chemical equilibrium?
Reasoning: A closed system does not allow exchange of matter with surroundings.
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Why is equilibrium not considered a state of no reaction?
Reasoning: Reactions continue but at equal rates, so no net change occurs.
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In a reversible reaction at equilibrium, what can be said about the system?
Reasoning: Microscopic reactions continue, but no overall change is observed.
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Which situation best represents chemical equilibrium?
Reasoning: Closed system with continuous phase exchange represents equilibrium.
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What is a key feature of reversible reactions that can reach equilibrium?
Reasoning: Reversible reactions can proceed in both directions.
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At equilibrium, if a small disturbance is introduced, what initially happens?
Reasoning: The system adjusts to restore equilibrium conditions.
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Which statement correctly describes equilibrium in terms of molecular activity?
Reasoning: Molecular activity continues dynamically in both directions.
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