FBISE, NCP & NBF-aligned resources for Classes 9–12
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Chemistry Chapter 8 : Topic 1
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A student performs a reaction in a sealed flask placed in a water bath. The reacting chemicals inside the flask are referred to as the system, while everything outside the flask (water bath, air, thermometer) is considered surroundings. Which statement best explains this classification?
Reasoning: In thermodynamics, the system is the part of the universe under study (reaction mixture), while surroundings include everything outside it that can exchange energy or matter with the system.
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A chemical reaction occurs in an open beaker, and heat is released to the surrounding air causing the temperature of the room to increase. Which statement correctly describes the energy transfer?
Reasoning: In an exothermic reaction, the system releases heat to the surroundings, increasing their temperature.
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A student observes that when ammonium nitrate dissolves in water, the container becomes cold. Which interpretation is most accurate?
Reasoning: Temperature drop indicates that the system absorbs heat from surroundings, making it an endothermic process.
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In a chemical reaction, the total energy of reactants is higher than that of products. What can be concluded about the system?
Reasoning: When products have lower energy than reactants, excess energy is released to surroundings as heat (exothermic reaction).
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Which statement best explains the concept of “universe” in chemical thermodynamics?
Reasoning: Theuniverse in thermodynamics includes both system and surroundings.
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A reaction is carried out in an insulated container so that no heat is lost or gained from surroundings. What type of system is this?
Reasoning: An isolated system does not exchange energy or matter with surroundings.
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During bond breaking in reactants, energy is absorbed, while bond formation releases energy. If more energy is released than absorbed, what is the net result?
Reasoning: If bond formation releases more energy than is required for bond breaking, overall energy is released (exothermic).
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Which of the following best explains why surroundings become hotter in an exothermic reaction?
Reasoning: Heat released by system is absorbed by surroundings, increasing their temperature.
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A chemical system absorbs 50 kJ of energy from surroundings. What happens to the surroundings?
Reasoning: Energy conservation means energy lost by surroundings is gained by system.
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In which case is the system correctly defined?
Reasoning: System includes all substances directly involved in chemical change.
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A reaction is performed in a calorimeter and temperature of water increases. What does this indicate?
Reasoning: Increase in surrounding water temperature shows heat released by system.
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Why is energy transfer important in chemical reactions?
Reasoning: Energy flow determines whether heat is absorbed or released.
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A system is said to be “closed” when:
Reasoning: Closed systems allow energy exchange but not matter exchange.
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Which statement correctly describes energy flow during endothermic reactions?
Reasoning: Endothermic reactions require energy input from surroundings.
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In a chemical reaction, if surroundings become colder, what is the correct interpretation?
Reasoning: Cooling of surroundings indicates heat absorption by system.
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Which of the following is the best example of an open system?
Reasoning: Open system exchanges both matter (steam) and energy with surroundings.
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The law of conservation of energy in chemical reactions implies that:
Reasoning: Energy is conserved and only transferred between system and surroundings.
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Which factor best explains why energy changes occur during chemical reactions?
Reasoning: Energy is absorbed in breaking bonds and released during bond formation.
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A reaction occurs in a perfectly insulated container. Which statement is true?
Reasoning: Insulated container prevents heat transfer, making it isolated in terms of energy.
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If a reaction releases energy slowly over time to surroundings, what will be observed?
Reasoning: Continuous energy release gradually warms surroundings.
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