FBISE, NCP & NBF-aligned resources for Classes 9–12
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Chemistry Chapter 5 : Topic 9
Electrical Conductivity
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A student observes two substances in a lab: Substance A is sodium chloride (NaCl), which forms a crystal lattice of oppositely charged ions, while Substance B is methane (CH₄), which consists of discrete molecules held together by weak intermolecular forces. Based on the nature of bonding and forces of attraction, which conclusion is most appropriate regarding their melting points?
Reasoning: Ionic compounds like NaCl have strong electrostatic attractions requiring high energy to break, while simple covalent molecules like CH₄ have weak intermolecular forces leading to low melting points.
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A chemist compares two solids: one is magnesium oxide (MgO), and the other is iodine (I₂). MgO has a giant ionic lattice, whereas iodine exists as simple molecular crystals. Despite both being solids at room temperature, their boiling points differ significantly. What is the main reason for this difference?
Reasoning: MgO has strong ionic bonds requiring very high energy to overcome, while iodine molecules are held together by weak dispersion forces.
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Consider three substances:
Reasoning: CO₂ has weak intermolecular forces, NaCl has strong ionic bonds, and diamond has a giant covalent network with extremely strong covalent bonds.
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A student states: “Covalent compounds always have lower melting points than ionic compounds.” However, graphite (a form of carbon) contradicts this idea partially. Which explanation best justifies this?
Reasoning: Graphite has strong covalent bonds in layers, but weak forces between layers, making it an exception in some physical properties.
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Two compounds X and Y are studied. X has a giant ionic structure, while Y is a simple molecular covalent compound. When heat is applied, Y melts easily but X does not. What is the most logical explanation?
Reasoning: Ionic bonds are much stronger than intermolecular forces in molecular compounds.
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Which of the following best explains why sodium chloride has a much higher boiling point than hydrogen chloride (HCl), even though both contain chlorine?
Reasoning: Ionic attraction in NaCl is much stronger than the dipole-dipole forces in HCl.
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Which statement correctly compares the forces of attraction in ionic and covalent substances?
Reasoning: Ionic compounds are held by strong electrostatic attraction, while molecular covalent compounds are held by weaker intermolecular forces.
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A substance melts at a very low temperature and easily evaporates at room temperature. Which structural explanation best fits this observation?
Reasoning: Weak intermolecular forces allow easy separation of molecules.
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Why does diamond have an extremely high melting point compared to wax, even though both are composed of carbon atoms?
Reasoning: Diamond is a network covalent solid; wax is molecular with weak forces.
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Which of the following best describes why ionic compounds are generally solid at room temperature?
Reasoning: Ionic lattice forces require high energy to break, keeping compounds solid.
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A student ranks substances based on boiling points: CO₂, NaCl, and CaO. Which correct order from lowest to highest boiling point is expected?
Reasoning: CO₂ has weak forces, NaCl has strong ionic bonds, CaO has even stronger ionic attraction due to higher charges.
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A group of students compares melting points of silicon dioxide (SiO₂) and carbon dioxide (CO₂). They find SiO₂ has a very high melting point while CO₂ is a gas at room temperature. What explains this difference?
Reasoning: SiO₂ has a strong network of covalent bonds requiring large energy to break.
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Why do molecular covalent compounds generally have low melting and boiling points?
Reasoning: Covalent bonds inside molecules remain intact; only intermolecular forces are broken during melting/boiling.
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Which statement best explains why calcium oxide (CaO) has a higher melting point than sodium chloride (NaCl)?
Reasoning: Ca²⁺ and O²⁻ have higher charges, leading to stronger electrostatic attraction.
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A compound is observed to have a high melting point and conducts electricity when molten. What type of bonding is most likely present?
Reasoning: Ionic compounds conduct electricity when molten due to free-moving ions and have high melting points due to strong ionic forces.
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