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Chemistry Chapter 5 : Topic 3
Electropositive and Electronegative Nature
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A student observes that metals tend to lose electrons during chemical reactions while non-metals tend to gain electrons. Which statement best explains this behavior?
Reasoning: Metals lose electrons easily because their outer electrons are loosely held, making them electropositive, while non-metals attract electrons strongly due to higher electronegativity.
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When sodium reacts with chlorine, sodium loses an electron and chlorine gains it. Which property of sodium is primarily responsible for this behavior?
Reasoning: Sodium is a metal with a strong tendency to lose electrons, which defines its electropositive character.
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Which statement best explains why non-metals such as chlorine and oxygen readily gain electrons during reactions?
Reasoning: Non-metals have almost filled outer shells, so gaining electrons helps them achieve a stable noble gas configuration, showing electronegative behavior.
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Which of the following properties mainly causes metals to exhibit electropositive character?
Reasoning: Metals generally have low ionization energy, meaning they lose electrons easily, giving them electropositive nature.
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Why do non-metals generally form negative ions during chemical reactions?
Reasoning: Non-metals have high electron affinity and electronegativity, allowing them to gain electrons and form anions.
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Which of the following periodic trends best explains why metals are electropositive?
Reasoning: Larger atomic size reduces nuclear attraction for valence electrons, making metals lose electrons easily.
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A student claims that fluorine is highly electronegative. Which observation supports this claim?
Reasoning: Electronegativity is the ability of an atom to attract electrons toward itself in a chemical bond.
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Which pair of elements would most likely form an ionic compound due to electropositive and electronegative behavior?
Reasoning: Sodium (metal) is electropositive and chlorine (non-metal) is electronegative, leading to electron transfer and ionic bond formation.
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Why do metals generally form cations while non-metals form anions?
Reasoning: Metals are electron donors (electropositive) forming cations, while non-metals are electron acceptors (electronegative) forming anions.
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A chemist compares magnesium and oxygen. Magnesium forms Mg²⁺ while oxygen forms O²⁻. Which explanation best accounts for this difference?
Reasoning: Magnesium is a metal (electropositive) and loses electrons, whereas oxygen is a non-metal (electronegative) and gains electrons.
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Which statement best relates electronegativity with the position of elements in the periodic table?
Reasoning: Across a period nuclear charge increases, attracting electrons more strongly; down a group atomic size increases, reducing attraction.
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A metal atom loses two electrons during a reaction. What is the most likely reason for this behavior?
Reasoning: Metals lose electrons to achieve stable noble gas configuration, demonstrating electropositive nature.
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Which property directly measures the ability of an atom to attract electrons toward itself in a chemical bond?
Reasoning: Electronegativity describes an atom’s tendency to attract shared electrons in a chemical bond.
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A comparison between potassium and fluorine shows opposite chemical behavior. Which explanation best accounts for this?
Reasoning: Potassium is highly electropositive, while fluorine is the most electronegative element.
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Why does the electropositive character of metals increase down a group in the periodic table?
Reasoning: Increased atomic size reduces nuclear attraction, making electron loss easier and increasing electropositive character.
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Which situation best demonstrates the electronegative nature of non-metals?
Reasoning: Chlorine gains electrons due to its strong attraction for electrons, showing electronegative behavior.
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In a chemical bond between a metal and a non-metal, the electron density is usually shifted toward the non-metal. Why?
Reasoning: Non-metals have higher electronegativity, so they attract bonding electrons more strongly.
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