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Chemistry Chapter 4 : Topic 14
Halogen Displacement Reactions
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A student adds chlorine water to a solution of potassium bromide. A reddish-brown color appears, indicating a chemical reaction has occurred. This observation is best explained by:
Reasoning: Chlorine is more reactive than bromine and displaces bromine from bromide ions, forming bromine (brown color).
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In a displacement reaction, when iodine solution is added to potassium chloride solution, no visible reaction occurs. The most appropriate conclusion is:
Reasoning: Reactivity decreases down the group (Cl₂>Br₂>I₂), so iodine cannot displace chloride ions.
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Which statement correctly describes halogens in displacement reactions?
Reasoning: More reactive halogens (like chlorine) displace less reactive halide ions (like bromide or iodide).
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When bromine water is added to potassium iodide solution, iodine is formed. This happens because:
Reasoning: Bromine acts as an oxidizing agent and converts iodide ions into iodine.
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Which halogen is the strongest oxidizing agent among the following?
Reasoning: Fluorine is the most reactive halogen and strongest oxidizing agent due to highest electronegativity.
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A displacement reaction occurs when chlorine is passed through potassium iodide solution. The correct observation is:
Reasoning: Chlorine displaces iodine from iodide ions, producing iodine which appears as purple vapors / solution.
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Which of the following correctly represents halogens acting as oxidizing agents?
Reasoning: Halogens gain electrons and oxidize other substances, so they act as oxidizing agents.
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In the reaction: Cl₂+2KBr → 2KCl+Br₂
Reasoning: Chlorine displaces bromine from bromide ions; it is a single displacement redox reaction.
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Which halide ion acts as the strongest reducing agent?
Reasoning: Iodide ions lose electrons most easily, making them the strongest reducing agents.
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A student observes that chlorine can displace bromine and iodine, but bromine can only displace iodine. This shows that:
Reasoning: Halogen reactivity decreases down Group 17 (Cl₂>Br₂>I₂).
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Why is chlorine considered a stronger oxidizing agent than bromine?
Reasoning: Chlorine has higher electronegativity and attracts electrons more strongly than bromine.
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When iodine is added to potassium bromide solution, no reaction occurs. This is because:
Reasoning: Iodine is less reactive and cannot oxidize bromide ions to bromine.
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Which best explains why halogens undergo displacement reactions?
Reasoning: More reactive halogens gain electrons by oxidizing halide ions.
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In halogen displacement reactions, the halogen that gets displaced always:
Reasoning: The displaced halogen is reduced to halide ions.
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Which statement correctly describes iodine in redox reactions?
Reasoning: Iodine / iodide ions act as reducing agents due to their tendency to lose electrons.
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